漏洞百出? 南通这两家机构联合发表的论文引发学者关注!

论文信息

2020年6月，南通市老年康复医院联合南通大学附属医院在Inorganic and Nano-Metal Chemistry(IF 1.716/Q3)期刊在线发表题为“Synthesis and anti-breast cancer activity on osteogenic sarcoma of a in/Na heterometallic coordination polymer”的论文。

论文作者：第一作者：Ying Liu(音译刘莹)；通讯作者：Wei-Dong Tang(音译唐伟东)。

论文质疑

质疑一

有学者质疑多处引用的参考文献与本文主题不相关，同时，多次引用了Kirillov，A.M.的文章作为参考文献。

与本文不相关的参考文献：

[6] Zhang D; Wang MM; Jiang N; Liu Y; Yu XN; Zhang HB，在3.5%的氯化钠溶液中，在低碳钢衬底上涂层的镍掺杂锌薄膜的电化学腐蚀行为。Int. J. Electrochem. Sci. 2020, 15, 4117–4126.

[7] Su J; Sheng Z; Xie L; Li G; Liu AX，基于快速拆分的超高频RFID系统防碰撞标签识别算法。IEEE Trans. Commun. 2019, 67, 2527–2538.

[8] Arshad M; Du HL; Javed MS; Maqsood A; Ashraf I; Hussain S; Ma W L; Ran HP，Sr掺杂BaTiO3陶瓷的制造、结构和频率依赖的电气和介质性能。Ceram. Int. 2020, 46, 2238–2246.

[9] Du H; Ma C; Ma W; Wang H，通过甘氨酸-硝酸酯工艺合成的掺杂铈SrBi4Ti4O15陶瓷的微观结构演变和介电性能。PAC 2018, 12, 303–312.

Kirillov A.M.的文章：

[15] Kirillov AM; Karabach YY; Kirillova MV; Haukka M; Pombeiro AJL. Topologically Unique 2D Heterometallic Cu(II)/Mg Coordination Polymer: Synthesis, Structural Features, and Catalytic Use in Alkane Hydrocarboxylation. Cryst. Growth Des. 2012, 12, 1069–1074.

[16] Kirillova MV; Kirillov AM;

Martins ANC; Graiff C; Tiripicchio A; Pombeiro AJL. Topologically Unique Heterometallic Cu(II)/Li Coordination Polymers Self-Assembled from N,N-Bis(2-Hydroxyethyl)-2-Aminoethanesulfonic Acid Biobuffer: Versatile Catalyst Precursors for Mild Hydrocarboxylation of Alkanes to Carboxylic Acids. Inorg. Chem. 2012, 51, 5224–5234.

[17] Kirillov AM; Coelho JAS; Kirillova MV; da Silva MFCG; Nesterov DS; Gruenwald KR; Haukka M; Pombeiro AJL. Bringing an “Old” Biological Buffer to Coordination Chemistry: New 1D and 3D Coordination Polymers with [Cu4(Hbes)4] Cores for Mild Hydrocarboxylation of Alkanes. Inorg. Chem. 2010, 49, 6390–6392.

[18] Sotnik SA; Polunin RA; Kiskin MA; Kirillov AM; Dorofeeva VN; Gavrilenko KS; Eremenko IL; Novotortsev VM; Kolotilov SV. Heterometallic Coordination Polymers Assembled from Trigonal Trinuclear Fe 2 Ni-Pivalate Blocks and Polypyridine Spacers: Topological Diversity, Sorption, and Catalytic Properties. Inorg. Chem. 2015, 54, 5169–5181.

[21] Gu JZ; Liang XX; Cai Y; Wu J; Shi ZF; Kirillov AM. Hydrothermal Assembly, Structures, Topologies, Luminescence, and Magnetism of a Novel Series of Coordination Polymers Driven by a Trifunctional Nicotinic Acid Building Block. Dalton Trans. 2017, 46, 10908–10925.

[22] Gu JZ; Cui YH; Wu J; Kirillov AM. A Series of Mixed-Ligand 2D and 3D Coordination Polymers Assembled from a Novel Multifunctional Pyridine-Tricarboxylate Building Block: Hydrothermal Syntheses, Structural and Topological Diversity, and Magnetic and Luminescent Properties. RSC Adv. 2015, 5, 78889–78901.

质疑二

图2c对晶体样品表面和内部(切割单个晶体后)的EDS分析图片与郭等人(2020)的图2c一致。